We received a heads up from @KingofToons that the remaining 25 DuckTales episodes that have not been released on DVD will soon be released as a Disney Movie Club exclusive (DuckTales Vol. 4) on September 11th.
You can join the Disney Movie Club here.
There were 100 episodes of DuckTales.
*Click the images below to purchase the previous DuckTales Volumes on Amazon.com
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DuckTales Volume 1 had 27 episodes.
DuckTales Volume 2 had 19 episodes plus the 5 episode pilot.
DuckTales Volume 3 had 24 episodes.
So after DuckTales Volume 4’s 25 episodes, all 100 episodes will be available on DVD.